A multiphoton ionization study of the photodissoclatlon dynamics of the 82 state of CH 3 0 NO

Two-color ( 1 + 1) REMPI (resonantly enhanced multiphoton ionization) photoelectron spectroscopy is used to probe the NO photofragments produced by the UV photodissociation of methyl nitrite, i.e., CH30NO + hv ...... CH30NO*(S2 ) ...... CH30· (X)+ NO(X, v, J). The photofragments are produced in their ground electronic states but with high rotational and translational energy. NO fragment angular distributions, rotational state distributions, and spatial alignment are determined by photoion and photoelectron detection. The initial state alignment is obtained by the CDAD (circularly dichroic angular distribution) technique for the first time. CDAD measurements for rotational levels with 35.5 = 0.4. This alignment is consistent with an "impulsive" dissociation mechanism in which photofragment recoil along the CH30-NO bond imparts substantial rotational angular momentum to the NO molecule resulting in a high-J state distribution and preferential rotation in the plane of dissociation. These measurements clearly establish the utility of the CDAD method for probing chemical processes in which spatial alignment plays an important role. Photoion angular distributions are used to probe correlations between the CH30NO transition dipole moment, NO fragment velocity, and angular momentum. These correlations reveal additional details of the photolysis mechanism.